First round

• Date: Tue, 12 Sep 2005 | Match: FC Barcelona 5-0 Levski Sofia
• Date: Wed, 27 Sep 2005 | Match: Werder Bremen 1-1 FC Barcelona
• Date: Wed, 18 Oct 2005 | Match: Chelsea FC 1-0 FC Barcelona
• Date: Tue, 31 Oct 2005 | Match: FC Barcelona 2-2 Chelsea FC
• Date: Wed, 22 Nov 2005 | Match: Levski Sofia 0-2 FC Barcelona
• Date: Tue, 5 Sep 2005 | Match: FC Barcelona 2-0 Werder Bremen

Second round

• Date: Wed, 21 Feb 2006 | Match: FC Barcelona 1-2 Liverpool
• Date: Tue, 6 Mar 2006 | Match: Liverpool 0-1 FC Barcelona